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71.
A Note On Surface Humidity Measurements In The Cold Canadian Environment   总被引:1,自引:0,他引:1  
In the cold Canadian environment, humidity measurements can be verydifficult to conduct. In this brief communication, humidity observationstaken by two different sensors at six remote Canadian Arctic locations arecompared. The observations collected by Vaisala HMP35CF sensors displaya strong tendency toward the ice saturation point whereas dew cell instrumentsexhibit significantly lower values of relative humidity with respect to ice (RHi).Humidity data collected by HMP35CF hygrometers are therefore unreliable sincethey are subject to persistent icing that lead them to record values of RHi near 100%, irrespective of the air temperature. The high humidity bias emerges atmeteorological stations mounted with the HMP35CF probes since these instrumentsare usually neither sheltered nor heated, and are not attended to at regular intervals. Thus, great care must be taken in utilizing humidity data recorded by HMP35CF sensors across the network of climate autostations in Canada.  相似文献   
72.
73.
Cosmogenic-nuclide exposure ages for 13 glacially transported boulders atop the Martha's Vineyard moraine, MA, USA, indicate that the southeastern margin of the Laurentide ice sheet reached its maximum extent during the last glaciation 23,200±500 yr ago. Another 10 age determinations from the younger Buzzards Bay moraine near Woods Hole, MA, indicate that this moraine complex was formed 18,800±400 yr ago. These ages correlate approximately with the terminations of cooling cycles recorded in Greenland ice cores and coeval ice-rafting events, suggesting that the marginal position of this sector of the ice sheet was tightly coupled to North Atlantic climate during the last glacial maximum.  相似文献   
74.
Low-molecular-weight (LMW) aqueous organic acids were generated from six oil-prone source rocks under hydrous-pyrolysis conditions. Differences in total organic carbon-normalized acid generation are a function of the initial thermal maturity of the source rock and the oxygen content of the kerogen (OI). Carbon-isotope analyses were used to identify potential generation mechanisms and other chemical reactions that might influence the occurrence of LMW organic acids. The generated LMW acids display increasing 13C content as a function of decreasing molecular weight and increasing thermal maturity. The magnitudes of observed isotope fractionations are source-rock dependent. These data are consistent with δ13C values of organic acids presented in a field study of the San Joaquin Basin and likely reflect the contributions from alkyl-carbons and carboxyl-carbons with distinct δ13C values. The data do not support any particular organic acid generation mechanism. The isotopic trends observed as a function of molecular weight, thermal maturity, and rock type are not supported by either generation mechanisms or destructive decarboxylation. It is therefore proposed that organic acids experience isotopic fractionation during generation consistent with a primary kinetic isotope effect and subsequently undergo an exchange reaction between the carboxyl carbon and dissolved inorganic carbon that significantly influences the carbon isotope composition observed for the entire molecule. Although generation and decarboxylation may influence the δ13C values of organic acids, in the hydrous pyrolysis system described, the nondestructive, pH-dependent exchange of carboxyl carbon with inorganic carbon appears to be the most important reaction mechanism controlling the δ13C values of the organic acids.  相似文献   
75.
Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.  相似文献   
76.
In this paper we employ mixed finite elements and numerically study an integrated two-dimensional model of fluid flow and compaction in a sedimentary basin. This model describes a single phase incompressible flow in a two-dimensional section of a sedimentary basin with vertical compaction. At each time step, an iterative algorithm is used to solve this model. The determination of the grid movement is based on the mass conservation and movement of sediments in the basin, while the mixed method is utilized to solve the fluid flow over the moving grid. Numerical experiments are presented to verify this iterative algorithm and show representative solutions for the model under consideration.  相似文献   
77.
Channel curvature produces secondary currents and a transverse sloping channel bed, along which the depth increases towards the outer bank. As a result deep pools tend to form adjacent to the outer bank, promoting bank collapse. The interaction of sediment grains with the primary and secondary flow and the transverse sloping bed also causes meanders to move different grain sizes in different proportions and directions, resulting in a consistent sorting pattern. Several models have been developed to describe this process, but they all have the potential to over‐predict pool depth because they cannot account for the influence of erodible banks. In reality, bank collapse might lead to the development of a wider, shallower cross‐section and any resulting flow depth discrepancy can bias associated predictions of flow, sediment transport, and grain‐size sorting. While bed topography, sediment transport and grain sorting in bends will partly be controlled by the sedimentary characteristics of the bank materials, the magnitude of this effect has not previously been explored. This paper reports the development of a model of flow, sediment transport, grain‐size sorting, and bed topography for river bends with erodible banks. The model is tested via intercomparison of predicted and observed bed topography in one low‐energy (5·3 W m?2 specific stream power) and one high‐energy (43·4 W m?2) study reach, namely the River South Esk in Scotland and Goodwin Creek in Mississippi, respectively. Model predictions of bed topography are found to be satisfactory, at least close to the apices of bends. Finally, the model is used in sensitivity analyses that provide insight into the influence of bank erodibility on equilibrium meander morphology and associated patterns of grain‐size sorting. The sensitivity of meander response to bank cohesion is found to increase as a function of the available stream power within the two study bends. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
78.
On the basis of one-dimensional theoretical water flow model, we demonstrate that the groundwater level variation follows a pattern similar to recharge fluctuation, with a time delay that depends on the characteristics of aquifer, recharge pattern as well as the distance between the recharge and observation locations. On the basis of a water budget model and the groundwater flow model, we propose an empirical model that links climatic variables to groundwater level. The empirical model is tested using a partial data set from historical records of water levels from more than 80 wells in a monitoring network for the carbonate rock aquifer, southern Manitoba, Canada. The testing results show that the predicted groundwater levels are very close to the observed ones in most cases. The overall average correlation coefficient between the predicted and observed water levels is 0.92. This proposed empirical statistical model could be used to predict variations in groundwater level in response to different climate scenarios in a climate change impact assessment.  相似文献   
79.
In this study, observed seismic attributes from shot gather 11 of the SAREX experiment are used to derive a preliminary velocity and attenuation model for the northern end of the profile in southern Alberta. Shot gather 11 was selected because of its prominent Pn arrivals and good signal to noise ratio. The 2-D Gaussian beam method was used to perform the modeling of the seismic attributes including travel times, peak envelope amplitudes and pulse instantaneous frequencies for selected phases. The preliminary model was obtained from the seismic attributes from shot gather 11 starting from prior tomographic results. The amplitudes and instantaneous frequencies were used to constrain the velocity and attenuation structure, with the amplitudes being more sensitive to the velocity gradients and the instantaneous frequencies more sensitive to the attenuation structure. The resulting velocity model has a velocity discontinuity between the upper and lower crust, and lower velocity gradients in the upper and lower crust compared to earlier studies. The attenuation model has Q p -1 values between 0.011 and 0.004 in the upper crust, 0.0019 in the lower crust and a laterally variable Q p -1 in the upper mantle. The Q p -1 values are similar to those found in Archean terranes from other studies. Although the results from a single gather are non-unique, the initial model derived here provides a self-consistent starting point for a more complete seismic attribute inversion for the velocity and attenuation structure.  相似文献   
80.
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